DaemonNews provides commercial training and support for FreeBSD. More information can be found at their BSD Mall site.
FreeBSD Services Ltd provide commercial support for FreeBSD in the UK (as well as selling FreeBSD on DVD). See their web site for more information.
The FreeBSD Mall provides commercial FreeBSD support. You can get more information at their web site.
Any other organizations providing training and support should contact the project in order to be listed here.